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铜钼分离工艺的研究现状与展望
引用本文:宋翔宇,张红涛,许来福,王文,张振.铜钼分离工艺的研究现状与展望[J].有色金属(选矿部分),2022(6):92-101.
作者姓名:宋翔宇  张红涛  许来福  王文  张振
作者单位:郑州大学化工学院,郑州大学化工学院,郑州大学化工学院,郑州大学化工学院,郑州大学化工学院
基金项目:国家自然科学资助(51874259)
摘    要:世界范围内铜钼共伴生矿产资源丰富,但硫化铜矿与辉钼矿因可浮性相近而成为选矿分离的一个难题。对常规铜钼分离工艺进行了较详细的介绍,并对氰化物、硫化物、巯基乙酸类、诺克斯药剂等几种常用的铜钼浮选分离抑制剂的作用机理与优缺点进行了分析论述;针对充氮浮选法、浮选柱浮选分离法、海水浮选技术、氧化浮选分离技术、电位控制浮选技术及超声预处理技术等几种新型铜钼分离技术,介绍了其研究进展并分析了其分选机理。文章还分析了目前铜钼分离工艺存在的主要问题,并探讨了今后的研究方向。

关 键 词:硫化铜矿  辉钼矿  铜钼分离  浮选工艺  抑制剂
收稿时间:2021/8/20 0:00:00
修稿时间:2021/8/25 0:00:00

A Review of Recent Advances in Techniques for Separation of copper-molybdenum
Authors:SONG Xiangyu  ZHANG Hongtao  XU Laifu  WANG Wen and ZHANG Zhen
Affiliation:School of Chemical Engineering,Zhengzhou University,School of Chemical Engineering,Zhengzhou University,School of Chemical Engineering,Zhengzhou University,School of Chemical Engineering,Zhengzhou University,School of Chemical Engineering,Zhengzhou University
Abstract:There are abundant mineral resources associated with copper and molybdenum in the world, but copper sulfide ore and molybdenite have become a difficult problem for mineral separation due to their similar floatability. The conventional copper-molybdenum separation process is introduced in more detail, and the action mechanism, advantages and disadvantages of several commonly used copper-molybdenum flotation separation depressants, such as cyanide, sulfide, thioglycolic acid, and Knox reagent, are analyzed. Discuss; for several new types of copper-molybdenum separation technologies, including nitrogen-filled flotation method, flotation column flotation separation method, seawater flotation technology, oxidation flotation separation technology, potential control flotation technology and ultrasonic pretreatment technology, etc., they are introduced Research progress and analysis of its sorting mechanism. The article also analyzed the main problems existing in the current copper-molybdenum separation process, and discussed the future research directions.
Keywords:chalcopyrite  molybdenite  copper-molybdenum separation  flotation process  depressant
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