| 预处理温度对SAPO-11催化丁烯骨架异构化性能的影响 |
| |
| 引用本文： | 李秀铭,廖克俭,佟明友,朱金剑.预处理温度对SAPO-11催化丁烯骨架异构化性能的影响[J].工业催化,2012,20(1):24-27. |
| |
| 作者姓名： | 李秀铭 廖克俭 佟明友 朱金剑 |
| |
| 作者单位： | 1.辽宁石油化工大学石油化工学院，辽宁 抚顺 113001;2.中国石化抚顺石油化工研究院，辽宁 抚顺 113001 |
| |
| 基金项目： | 中国石化企业委托开发项目（210038） |
| |
| 摘 要： | 采用水热合成法合成的SAPO-11分子筛，经酸洗、干燥和焙烧处理得H-SAPO-11分子筛，考察了预处理温度对催化剂物化性能的影响，采用XRD、XRF、IR和NH3-TPD等手段对催化剂进行表征。实验证明，500 ℃预处理后H-SAPO-11分子筛的结构缺陷较少，B酸位较多，骨架更完美；将其成型制成催化剂，对丁烯骨架异构化反应显示更优良的催化活性、选择性和稳定性。
|
| 关 键 词： | 催化剂工程 SAPO-11分子筛 H-SAPO-11分子筛 预处理温度 丁烯骨架异构化 |
Effect of pretreatment temperature on the performance of SAPO-11 catalyst for the skeletal isomerization of n-butene |
| |
| LI Xiuming
,
LIAO Kejian
,
TONG Mingyou
,
ZHU Jinjian.Effect of pretreatment temperature on the performance of SAPO-11 catalyst for the skeletal isomerization of n-butene[J].Industrial Catalysis,2012,20(1):24-27. |
| |
| Authors: | LI Xiuming LIAO Kejian TONG Mingyou ZHU Jinjian |
| |
| Affiliation: | 1.School of Petrochemical Engineering, Liaoning Shihua University, Fushun 113001, Liaoning, China; 2.Sinopec Fushun Research Institute of Petroleum and Petrochemicals, Fushun 113001, Liaoning, China |
| |
| Abstract: | SAPO-11 molecular sieve was synthesized by hydrothermal method. H-SAPO-11 molecular sieve was prepared by oxalic acid washing, dryness and calcination. The influence of pretreatment temper- ature on the physieochemical properties of the catalyst was investigated. The catalyst was characterized by XRD, XRF, IR and NH3-TPD. The results indicated that H-SAPO-11 molecular sieve pretreated at 500 ℃ had higher crystallinity and more Brtonsted acid sites, and exhibited better catalytic activity, selectivity and stability for the skeletal isomerization reaction of n-butene. |
| |
| Keywords: | catalyst engineering SAP0-11 molecular sieve H-SAP0-11 molecular sieve pretreatmenttemperature butene skeletal isomerization |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
| 点击此处可从《工业催化》浏览原始摘要信息 |
|
点击此处可从《工业催化》下载全文 |
