| 叠氮桥联的三苯基膦二铜(I)配合物[Cu_2(N_3)_2(PPh_3)_4]的晶体结构及热性能分析 |
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| 引用本文： | 栗春蕾,马怀波,于广水.叠氮桥联的三苯基膦二铜(I)配合物[Cu_2(N_3)_2(PPh_3)_4]的晶体结构及热性能分析[J].青岛科技大学学报,2005(1). |
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| 作者姓名： | 栗春蕾 马怀波 于广水 |
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| 作者单位： | 青岛科技大学配位化学研究所 山东青岛266042
(栗春蕾，马怀波)，青岛科技大学配位化学研究所 山东青岛266042(于广水) |
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| 摘 要： | 通过X 射线单晶衍射,确定了Cu2 (N3 )2 (PPh3 )4 ]的晶体结构。晶体结构属于单斜晶系,空间群为P21 /c, 晶胞参数为:a=2. 348 8(5)nm, b=1 .373 8(3)nm, c=2 0099(4)nm; β=106 42(3)°, Z=4。配合物 Cu2 (N3 )2 (PPh3 )4 ]的每个分子是由 2个叠氮基团桥联的双核铜分子,铜(I)离子采取四配位的变形四面体几何构型,每个铜原子分别与 2个三苯基膦的磷原子及 2个叠氮基团的氮原子形成配位键。热重分析显示标题化合物有较高的热稳定性。
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| 关 键 词： | 双核铜配合物 叠氮桥联基团 晶体结构 热性能 |
Crystal Structure and Thermal Stability of Binuclear Copper(I) Complex with Triphenylphosphine Ligand Bridged by Azide Group |
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| LI Chun-lei,MA Huai-bo,YU Guang-shui.Crystal Structure and Thermal Stability of Binuclear Copper(I) Complex with Triphenylphosphine Ligand Bridged by Azide Group[J].Journal of Qingdao University of Science and Technology:Natutral Science Edition,2005(1). |
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| Authors: | LI Chun-lei MA Huai-bo YU Guang-shui |
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| Abstract: | The crystal and molecular structure of the complex of \Cu_ 2(N_ 3)_ 2(PPh_ 3)_ 4\] was determined by X-ray crystallography. It crystalizes in monoclinic system, space group P2_1/c with lattice parameters:a=2.348 8(5)nm, b=1.373 8(3)nm, c=2.009 9(4)nm,β=106.42(3)°, Z=4. In \Cu_ 2(N_ 3)_ 2(PPh_ 3)_ 4\]_ , two copper ions are bridged by two azide moieties. Each copper atom lies in the distorted tetrahedral environment, and coordinates with P atoms of triphenylphosphine ligands and N atoms of azide groups. The title compound was of higher thermal stability. |
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| Keywords: | binuclear copper complex bridging azide group crystal structure thermal stability |
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