Magnetic Phase Transitions in Cobalt Chromite Nanoparticles

Cobalt chromite (CoCr₂O₄), an insulating normal spinel compound, is a potential multiferroic material. We report that pure, nanosize CoCr₂O₄ particles are synthesized through a conventional coprecipiation technique by controlling the pH of the precipitation. Both single-crystal and polycrystalline samples develop long-range ferrimagnetic order below the Curie temperature, T _c (97 K), and a sharp phase transition at T _s??31 K, attributed to the onset of long-range spiral magnetic order. However, we observed a transition from paramagnetic to superparamagnetic phase at T _c. Further lowering the temperature below T _c (97 K), the superparamagnetic phase transforms to ferrimagnetic phase at blocking temperature, T _b, which is found to be between 50 and 60 K. This intermediate superparamagnetic phase in between paramagnetic and long-range ferrimagnetic phases is attributed to a nanosize effect.