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The role of disorder on the AC and DC electrical conductivity of vapour grown carbon nanofibre/epoxy composites
Authors:P. Cardoso  J. Silva  D. Klosterman  J.A. Covas  F.W.J. van Hattum  R. Simoes  S. Lanceros-Mendez
Affiliation:1. Centre/Department of Physics, University of Minho, Campus de Gualtar, 4710-057 Braga, Portugal;2. Institute for Polymers and Composites – IPC/I3N, University of Minho, Campus de Azurém, 4800-058 Guimarães, Portugal;3. Chemical & Materials Engineering, University of Dayton, 300 College Park, Dayton, OH 45469-0246, USA;4. School of Technology, Polytechnic Institute of Cávado and Ave., Campus do IPCA, 4750-810 Barcelos, Portugal
Abstract:
Four dispersion methods were used for the preparation of vapour grown carbon nanofibre (VGCNF)/epoxy composites. It is shown that each method induces certain levels of VGCNF dispersion and distribution within the matrix, and that these have a strong influence on the composite electrical properties. A homogenous VGCNF dispersion does not necessarily imply higher electrical conductivity. In fact, it is concluded that the presence of well distributed clusters, rather than a fine dispersion, is more important for achieving larger conductivities for a given VGCNF concentration. It is also found that the conductivity can be described by a weak disorder regime.
Keywords:A. Nano composites   A. Polymer&ndash  matrix composites (PMCs)   B. Electrical properties
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