| 阻燃剂DTBBP的合成及其性能测试 |
| |
| 引用本文： | 王锐,陶文亮,安燕,刘守新.阻燃剂DTBBP的合成及其性能测试[J].塑料助剂,2009(5):16-21. |
| |
| 作者姓名： | 王锐 陶文亮 安燕 刘守新 |
| |
| 作者单位： | 1. 东北林业大学材料科学与工程学院,哈尔滨,150040
2. 贵州大学化学工程学院,贵阳,550003 |
| |
| 基金项目： | 致谢：感谢贵州大学化学工程学院秦军副教授及其硕士研究生王洋在实验工作中给予的支持和帮助. |
| |
| 摘 要： | 以2,4-二叔丁基苯酚为原料合成了可用作阻燃剂的化合物4,4＇,6,6＇-四叔丁基-2,2＇-二苯基]酸式磷酸酯二乙胺（DTBBP）,用元素含量分析、红外光谱、核磁共振氢谱、质谱等方法表征了产物的结构,并进行了其热性能测试。用极限氧指数的测试、水平燃烧试验及垂直燃烧试验等方法测试了其阻燃性,并用DSC-TG谱图进行了说明。结果表明DTBBP有一定的阻燃效果。
|
| 关 键 词： | 2 4-二叔丁基苯酚 （4 4＇ 6 6＇-四叔丁基-2 2＇-二苯基）酸式磷酸酯二乙胺 阻燃剂 合成 表征 阻燃性 |
Synthesis and Property Determination for Flame Retardant DTBBP |
| |
| Wang Rui,Tao Wen-liang,An Yan,Liu Shou-xin.Synthesis and Property Determination for Flame Retardant DTBBP[J].Plastic Additives,2009(5):16-21. |
| |
| Authors: | Wang Rui Tao Wen-liang An Yan Liu Shou-xin |
| |
| Affiliation: | 1. College of Material Science and Engineering, Northeast Forestry University, Harbin, 150040; 2. College of Chemical Engineering, Guizhou University, Guiyang, 550003) |
| |
| Abstract: | 4,4＇,6,6＇-Tetra-tert-butyl（-2,2＇-biphenyl）hydroxyl] phosphate diethylamine（DTBBP）,a compound that can be used as phosphorous-nitrogen flame retardant,was synthesized from 2,4-di-tert-butylphenol and characterized by means of element content analysis,IR,1H NMR,LC-MS,and so on.The DSC and TG spectra of DTBBP was also determined.The flame retardancy was tested by means the LOI,and horizontal and vertical burning test.The results were explained by the DSC-TG spectra.It was indicated that DTBBP has flame retardancy in a certain extent. |
| |
| Keywords: | 2 4-di-t-butylphenol （4 4’ 6 6’-tetra-tert-butyl-2 2’-biphenyl） hydroxyl phosphate diethylamine flame retardant synthesis characteristic flame retardancy |
| 本文献已被 维普 万方数据 等数据库收录！ |
|
