(BETS)2[RuX5NO] (X = Cl, Br): An Explanation of Different Conductive Properties Through Structural and Spectroscopic Studies |
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| Authors: | L Valade I Malfant A Glaria J-F Lamère B Garreau de Bonneval D de Caro S Vincendeau K Jacob M-L Doublet A Zwick |
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| Affiliation: | (1) Condensed Molecular Materials Laboratory, RIKEN, 2-1, Hirosawa, Wakoshi, 351-0198 Saitama, Japan |
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| Abstract: | For the development of new crystal and electronic structures in molecular conductors, dimeric tetrathiafulvalene (TTF) and
tetraselenafulvalenes (TSFs)1–3 linked by single or double methyl antimony bridge(s) have been prepared and their neutral crystal structures have been investigated.
The donor2 (cis-2) forms a metallic cation radical salt with tetracyanoquinodimethane (TCNQ) containing one-dimensional array interactions. |
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