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| 2-巯基吡啶与Cu(I)配合物的合成、晶体结构及光物理性质 | |
| 引用本文： | 于玲. 2-巯基吡啶与Cu(I)配合物的合成、晶体结构及光物理性质[J]. 河北化工, 2012, 0(10): 42-44 |
| 作者姓名： | 于玲 |
| 作者单位： | 邢台学院 |
| 基金项目： | 邢台学院2011年科研立项校级课题(编号:XTXY11Y11) |
| 摘 要： | 利用Cu(I)前体[Cu(CH3CN)4]BF4与配体2-巯基吡啶、邻菲罗啉进行反应,合成了一种新型铜(I)配合物:{[Cu3(py2tH)6](BF4)3.H2O}n。运用X-射线单晶衍射方法确定了其晶体结构。同时,利用现代波谱方法对配合物的光物理性质进行研究。发射光谱显示在632nm处的发射峰属于金属到配体的电荷跃迁,即MLCT。 |
| 关 键 词： | Cu(I)配合物 合成 晶体结构 光物理性质 |
Synthesis,Crystal Structure and Photophysical Property of the Complex of 2-Mercaptopridine with Cu(I) |
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| YU Ling. Synthesis,Crystal Structure and Photophysical Property of the Complex of 2-Mercaptopridine with Cu(I)[J]. Hebei Chemical Engineering and Industry, 2012, 0(10): 42-44 | |
| Authors: | YU Ling |
| Affiliation: | YU Ling(Xingtai University,Xingtai 054001,China) |
| Abstract: | A new Cu(I) complex {[Cu3(py2tH)6](BF4)3·H2O}n was synthesized from [Cu(CH3CN)4]BF4,2-mercaptopridine and phenanthroline.The structure of the complex was determined by X-ray diffraction single crystal.The photophysical property was obtained from the analysis of the modern spectroscopic methods.The emission peak at 632 nm belongs to metal to ligand charge transition(MLCT). |
| Keywords: | Cu(I) complex synthesis crystal structure photophysical property |
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