The road to non-heme oxoferryls and beyond |
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Authors: | Que Lawrence |
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Affiliation: | Department of Chemistry and Center for Metals in Biocatalysis, University of Minnesota, Minneapolis, Minnesota 55455, USA. |
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Abstract: | Oxoiron(IV) species are often implicated in the catalytic cycles of oxygen-activating non-heme iron enzymes. The paucity of suitable model complexes stimulated us to fill this void, and our synthetic efforts have afforded a number of oxoiron(IV) complexes. This Account provides a chronological perspective of the observations that contributed to the generation of the first non-heme iron(IV)-oxo complexes in high yield and summarizes their salient properties to date. |
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