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Incorporation of polyoxometalate-based acid–base pair into a sulfonated MIL-101 for achieving proton-conduction materials with high proton conductivity and high stability
作者姓名:Wan-Yu Zhang  Ying Lu  Zhuo Li  Yang Wang  Xiu-Wei Sun  Qian Wang  Zhong Zhang  Shu-Xia Liu
基金项目:financially supported by the National Natural Science Foundation of China (Grant Nos. 22071019 and 21872021);
摘    要:Currently,it is of great significance to develop new proton-conduction materials with high proton conductivity,high stability,and good conducting durability to meet the demands of fuel cell and sensors.Herein,we prepared two composites DETAHPW@MIL-101-SO3 H 1 and TETA-HPW@MIL-101-SO3 H 2(DETA=diethylenetriamine,HPW=H3 PW12040·xH2 O,MIL=Material Institut Lavoisier,TETA=triethylenetetramine) by encapsulating polyoxometalate(POM) and organic amine into a ...

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