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盐湖卤水碳酸锂提取工艺过程研究
引用本文:李燕茹,袁建军,朱亮,沙作良,杨美洁,左玥华.盐湖卤水碳酸锂提取工艺过程研究[J].无机盐工业,2013,45(7):12-14.
作者姓名:李燕茹  袁建军  朱亮  沙作良  杨美洁  左玥华
作者单位:天津科技大学天津市海洋资源与化学重点实验室,天津 300457
基金项目:国家自然科学基金资助项目,天津市自然科学基金资助项目,天津市自然科学基金资助项目
摘    要:青藏高原的盐湖卤水锂储量丰富,通过盐田蒸发浓缩,去除卤水中的绝大部分Na+、K+、SO42-、Cl-、Mg2+,可以使镁锂比降到8~12,锂离子质量分数也可达到0.5%以上。以蒸发浓缩后的富锂卤水为原料,选用碳酸钠和氢氧化钠为沉淀剂分两步沉淀除镁,之后用碳酸钠为沉淀剂提锂,通过对此工艺过程中的各个阶段进行实验,最终可以得到纯度和收率较高的粗级碳酸锂产品。

关 键 词:盐湖卤水  提锂工艺  沉淀法  碳酸锂  

Research on extraction process of lithium carbonate from salt lake brine
Li Yanru , Yuan Jianjun , Zhu Liang , Sha Zuoliang , Yang Meijie , Zuo Yuehua.Research on extraction process of lithium carbonate from salt lake brine[J].Inorganic Chemicals Industry,2013,45(7):12-14.
Authors:Li Yanru  Yuan Jianjun  Zhu Liang  Sha Zuoliang  Yang Meijie  Zuo Yuehua
Affiliation:Tianjin Key Laboratory of Marine Resources and Chemistry,Tianjin University of Science & Technology,Tianjin 300457,China
Abstract:The salt lake brine in Tibetan Plateau has a rich lithium reserves.After the process of evaporation in the salt pan, the most impurities,such as Na+,K+,SO42-,Cl-,and Mg2+ in the brine can be removed.At the same time,the ratio of Mg/Li is decreased to the range of 8~12 and the mass fraction of lithium ion can be concentrated to over 0.5%.The magnesium ions in the evaporated lithium-rich brine are precipitated with the sodium carbonate and sodium hydroxide as precipitators,and then the lithium is extracted with sodium carbonate as precipitator.After a series of experiments in all the stages of the process,coarse lithium carbonate with relatively higher purity and yield is finally obtained.
Keywords:saline lake brine  extraction process of lithium  precipitation method  lithium carbonate
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