Influence of heat-treatment environment on Ni-ferrite nanoparticle formation from coconut water precursor

The kinetics of formation of NiFe₂O₄ nanoparticles were investigated where the nanoparticles were produced by the proteic-sol–gel method using coconut water followed by annealing in (i) air, (ii) air in the presence of boron nitride (BN), or (iii) nitrogen. The sample dried at 473 K for 5.5 h was composed of small disordered NiFe₂O₄ nanoparticles in a superparamagnetic state as determined from Mössbauer spectroscopy. In general, heat treatment at high temperature leads to a nanocomposite rich in NiFe₂O₄. In air, annealing at 1173 K for 8 h favored the formation of the magnetically ordered NiFe₂O₄ inverse spinel structure, with bulk characteristics and average crystal sizes of approximately 66 nm. In a nitrogen atmosphere and in compacted BN powder under air atmosphere, the NiFe₂O₄ spinel structure stabilized for temperatures up to 873 and 773 K, respectively, however, decomposition of the NiFe₂O₄ phase into other undesired structures was observed above 873 K.