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Li_2O-B_2O_3-SiO_2掺杂低温烧结CLST陶瓷的介电性能
引用本文:李飞龙,黄金亮,杨留栓,顾永军,李谦.Li_2O-B_2O_3-SiO_2掺杂低温烧结CLST陶瓷的介电性能[J].电子元件与材料,2009,28(5).
作者姓名:李飞龙  黄金亮  杨留栓  顾永军  李谦
作者单位:河南科技大学,材料科学与工程学院,河南,洛阳,471003
基金项目:河南省杰出青年科学基金,河南省国际科技合作计划 
摘    要:通过Li2O-B2O3-SiO(2LBS)玻璃的有效掺杂,低温液相烧结制备了16CaO-9Li2O-12Sm2O3-63TiO(2CLST)陶瓷。研究了LBS掺杂量对其烧结性能、相组成及介电性能的影响。结果表明:通过掺杂LBS,使CLST陶瓷的烧结温度由1300℃降至1000℃,且无第二相生成。随LBS掺杂量的增加,tanδ显著降低,τf趋近于零。当w(LBS)为10%时,CLST陶瓷在1000℃烧结3h获得最佳介电性能:tanδ为0.0045,τf为4×10–6/℃,虽然εr由105.0降至71.0,但仍属于高εr范围。

关 键 词:无机非金属材料  微波介质陶瓷  CaO-Li2O-Sm2O3-TiO2  液相烧结  助剂

Low temperature sintering and dielectric properties of CaO-Li_2O-Sm_2O_3-TiO_2 ceramics doped with Li_2O-B_2O_3-SiO_2 glass
LI Feilong,HUANG Jinliang,YANG Liushuan,GU Yongjun,LI Qian.Low temperature sintering and dielectric properties of CaO-Li_2O-Sm_2O_3-TiO_2 ceramics doped with Li_2O-B_2O_3-SiO_2 glass[J].Electronic Components & Materials,2009,28(5).
Authors:LI Feilong  HUANG Jinliang  YANG Liushuan  GU Yongjun  LI Qian
Affiliation:School of Materials Science and Engineering;Henan University of Science and Technology;Luoyang 471003;Henan Province;China
Abstract:To reduce the sintering temperature of 16CaO-9Li2O-12Sm2O3-63TiO2 (CLST) ceramics, the CLST ceramics were prepared by the traditional ceramic process at a lower sintering temperature and using Li2O-B2O3-SiO2 (LBS) glass as a liquid phase sintering assistants. The effects of LBS doping amounts on the sintering behaviours, phase compositions and dielectric properties of CLST ceramics were investigated. The results indicate that LBS glass can be used as sintering assistants to reduce the sintering temperature ...
Keywords:CaO-Li2O-Sm2O3-TiO2
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