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Highly luminescent monodisperse CdSe nanoparticles synthesized in aqueous solution
Authors:Xianfeng Chen  John L. Hutchison  Peter J. Dobson  Gareth Wakefield
Affiliation:(1) Department of Materials, University of Oxford, Parks Road, Oxford, OX1 3PH, UK;(2) Oxford University Begbroke Science Park, Sandy Lane, Kidlington, Oxford, OX5 1PF, UK;(3) Oxonica Materials Ltd., 7 Oxford University Begbroke Science Park, Oxford, OX5 1PF, UK
Abstract:Simple routes to synthesize highly photoluminescent monodisperse thiol-capped CdSe nanoparticles are reported. The as-synthesized water-soluble CdSe nanoparticles possess higher photoluminescence quantum efficiency (up to 22%), smaller values of full width of half-maximum of photoluminescence spectra (down to 31 nm), higher photostability, and better monodispersity compared with the nanoparticles made from other aqueous routes. The quality of CdSe nanoparticles prepared by our route compares very favourably with those prepared in organic solution.
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