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不同添加剂对SrAl2O4:(Eu,Dy)磷光体发光性能的影响
引用本文:沈毅,张平,郑振太,曲远方.不同添加剂对SrAl2O4:(Eu,Dy)磷光体发光性能的影响[J].硅酸盐学报,2006,34(10):1187-1190.
作者姓名:沈毅  张平  郑振太  曲远方
作者单位:1. 先进陶瓷与加工技术教育部重点实验室,天津大学材料学院,天津,300072;河北理工大学,河北,唐山,063009
2. 先进陶瓷与加工技术教育部重点实验室,天津大学材料学院,天津,300072
3. 先进陶瓷与加工技术教育部重点实验室,天津大学材料学院,天津,300072;河北工业大学,天津,300130
基金项目:河北省重大科学技术项目
摘    要:在较低的温度下用燃烧合成法快速合成了 Eu2 ,Dy3 掺杂的SrAl2O4长余辉磷光体发光材料.研究了P2O5,CaF2,H3BO3,NaF 几种添加剂对SrAl2O4:(Eu,Dy)粉体发光性能的影响.结果发现:H3BO3和P2O5的添加有利于改善磷光体的发光性能,而在配料中加入CaF2和NaF,磷光体发光效率降低.随着这几种添加剂的加入,SrAl2O4:(Eu,Dy)磷光体材料发射光谱的主发射峰不同程度的出现蓝移.根据实验结果分析了添加剂的作用机理.

关 键 词:添加剂  铝酸锶  长余辉发光材料
文章编号:0454-5648(2006)10-1187-04
收稿时间:02 24 2006 12:00AM
修稿时间:06 18 2006 12:00AM

INFLUENCE OF DIFFERENT ADDITIVES ON THE LUMINESCENCE PROPERTIES OF SrAl2O4:(Eu, Dy)PHOSPHORS
SHEN Yi,ZHANG Ping,ZHENG Zhentai,QU Yuanfang.INFLUENCE OF DIFFERENT ADDITIVES ON THE LUMINESCENCE PROPERTIES OF SrAl2O4:(Eu, Dy)PHOSPHORS[J].Journal of The Chinese Ceramic Society,2006,34(10):1187-1190.
Authors:SHEN Yi  ZHANG Ping  ZHENG Zhentai  QU Yuanfang
Affiliation:1.Key Laboratory for Advanced Ceramics and Machining Technology of Ministry of Education, School of Materials Science and Engineering, Tianjin University, Tianjin 300072; 2. Hebei Polytechnic University, Tangshan 063009, Hebei; 3. Hebei University of Technology, Tianjin 300130, China
Abstract:Strontium aluminate co-doped with Eu2+,Dy3+phosphor powders were rapidly prepared at lower temperatures by combus-tion synthesis.The influence of P2O5,CaF2,H3BO3 and NaF additives on the luminescence properties of SrAl2O4:(Eu,Dy)phosphors was studied.The results indicate that the luminescence properties of SrAl2O4:(Eu,Dy)phosphors are improved by doping of the H3BO3 and P2O5,but suppressed by doping of CaF2 and NaF.The main emission peaks on the emission spectra doped with the addi-tives tend to blue shift compared to that without additives.According to the results,the mechanism of the additives in phosphors was analyzed.
Keywords:additives  strontium aluminates  long afterglow phosphor
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