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卟啉锌/锰配合物的合成与表征
引用本文:任丽磊,张光霞.卟啉锌/锰配合物的合成与表征[J].精细与专用化学品,2010,18(3):42-43.
作者姓名:任丽磊  张光霞
作者单位:廊坊师范学院化学系,河北,廊坊,065000
摘    要:用5,10,15,20-四(4氯苯基)卟啉或5-(4-羟基苯基)-10,15,20三(4-氯苯基)卟啉与四水氯化锰、醋酸锌反应,合成了5,10,15,20-四(4-氯苯基)卟啉锌、5,10,15,20-四(4-氯苯基)卟啉锰、5-(4-羟基苯基)-10,15,20-三(4-氯苯基)卟啉锌、5(4-羟基苯基)-10,15,20-三(4-氯苯基)卟啉锰四种金属卟啉,并用UV-Vis、IR对其结构进行了表征。

关 键 词:卟啉  金属卟啉  合成

Synthesis and characterization of porphyrin's Zn and Mn complexes
REN Li-lei,ZHANG Guang-xia.Synthesis and characterization of porphyrin's Zn and Mn complexes[J].Fine and Specialty Chemicals,2010,18(3):42-43.
Authors:REN Li-lei  ZHANG Guang-xia
Affiliation:(Department of Chemistry,Normal College of Langfang,Langfang 065000,China)
Abstract:5,10,15,20-tetra(4-chlorophenyl) porphyrin Zn,5,10,15,20-tetra(4-chlorophenyl) porphyrin Mn,5-(4-hydroxyphenyl)-10,15,20-tri(4-chlorophenyl)porphyrin Zn and 5-(4-hydroxyphenyl)-10,15,20-tri(4- chlorophenyl)porphyrin Mn were synthesized using the reaction between 5,10,15,20-tetra(4-chlorophenyl)porphyrin or 5-(4-hydroxyphenyl)-10,15,20-tri(4-chlorophenyl) porphyrin and manganese chloride tetrahydrate,zinc acetate.Their structures were characterized by UV-Vis spectrum and IR.
Keywords:porphyrin  metalloporphyrin  synthesis
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