电磁场对碳酸钙成核诱导期影响的实验研究

基于电导率随滴定液容积变化特征与碳酸钙结晶过程的对比分析,研究了电磁场作用对碳酸钙结晶过程中成核诱导期的影响。在不同频率的电磁场作用下观察了碳酸钙溶液临界过饱和度及成核诱导期的变化,大量实验结果表明:电磁场作用能够降低碳酸钙溶液临界过饱和度,加速碳酸钙成核,缩短成核诱导期。通过机理分析,电磁场对碳酸钙成核过程的主要作用为:在洛伦兹力的影响下,溶液中的Ca2+及CO32-等带电离子运动方向要向相反方向偏离,增加了Ca2+和CO32-离子间的碰撞几率,加快新相晶核的生成。

Study on Electromagnetic Field Influence on Nucleation Induction Period of Calcium Carbonate

Based on analyzing the conductivity which changing with titration volume and comparing the calcium carbonate fouling process,the electromagnetic field influence on nucleation induction period of calcium carbonate crystallization was analyzed; and the changes of critical supersaturation ratio and nucleation induction period of calcium carbonate solution were observed at the electromagnetic field with different frequencies.Experiment results show that：the electromagnetic field influence can decrease the critical supersaturation ratio,and can speed up the nucleation rate and shorten nucleation induction period.The mechanism analysis shows that the main influence of electromagnetic field on calcium carbonate nucleation process is under the Lorentz force,the charge ions like Ca2＋ and CO32-can move in opposite direction so as to increase collision probability of Ca2＋ and CO32-and to speeded up the formation of new phase crystal nucleus.