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复合膜法火电厂烟气捕水性能的实验研究
引用本文:陈海平,仲雅娟,周亚男,兰俊杰,杜文韬.复合膜法火电厂烟气捕水性能的实验研究[J].中国电力,2015,48(7):63-67.
作者姓名:陈海平  仲雅娟  周亚男  兰俊杰  杜文韬
作者单位:1. 华北电力大学 能源动力与机械工程学院,北京 102206;2. 北方联合电力有限责任公司,内蒙古 呼和浩特 010010;3. 东方电气集团东方锅炉股份有限公司,四川 自贡 643001
摘    要:复合膜法捕集火电厂烟气中的水蒸气有望成为火电厂节水的一条有效途径。选用聚醚砜(PES)作为中空纤维膜支撑层材料,磺化聚醚醚酮(SPEEK)作为中空纤维膜涂层材料,制作了用于实验研究的SPEEK- PES中空纤维复合膜;采用模拟烟气(H2O/N2)在实验台上研究了不同磺化度的SPEEK涂层、吹扫气流速、烟气温度等对中空纤维复合膜捕水性能的影响。实验结果表明,复合膜中SPEEK的磺化度不是越高越好;吹扫气流速也存在一个最优值;在实验温度范围(40~70 ℃)内,随着温度的提升,复合膜的捕水性能有所提高。

关 键 词:火电厂  烟气  水蒸气  中空纤维复合膜  捕水  聚醚砜  磺化聚醚醚酮  
收稿时间:2015-03-15

Experimental Study on Flue Gas Water Recovery Performance Using Composite Membranes in Thermal Power Plants
CHEN Haiping,ZHONG Yajuan,ZHOU Yanan,LAN Junjie,DU Wentao.Experimental Study on Flue Gas Water Recovery Performance Using Composite Membranes in Thermal Power Plants[J].Electric Power,2015,48(7):63-67.
Authors:CHEN Haiping  ZHONG Yajuan  ZHOU Yanan  LAN Junjie  DU Wentao
Affiliation:1. School of Energy, Power and Mechanical Engineering, North China Electricity Power University, Beijing 102206, China; 2. North United Power Corporation, Hohhot 010010, China; 3. Dongfang Electric Corporation, Dongfang Boiler Group Co., Ltd., Zigong 643001, China
Abstract:Water recovery by composite membranes from flue gas is expected to be an effective technology for water saving in thermal power plants. In this study, the SPEEK-PES hollow fiber composite membrane is made by using polyether sulfone (PES) as the hollow fiber membrane support layer material and sulfonated polyether ether ketone (SPEEK) as the coating material for the hollow fiber membrane; the effect of different sulfonation degrees of SPEEK coating, purge gas flow rate and flue gas temperature on the water capture performance of hollow fiber composite membrane is studied with the simulated flue gas(H2O/N2). The experimental results show that higher sulfonation degree of SPEEK of the composite membrane does not mean better; the purge gas flow rate also has an optimal value; in the range of experimental temperatures(40~70 ℃), with the temperature increasing, the water capture performance of the composite membrane improves.
Keywords:thermal power plant  flue gas  water vapor  hollow fiber composite membrane  vapor capture  polyether sulfone  sulfonated polyether ether ketone
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