Aqueous leachability of metakaolin-based geopolymers with molar ratios of Si/Al = 1.5-4 |
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| Authors: | Z Aly ER Vance DS Perera JV Hanna CS Griffith J Davis D Durce |
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| Affiliation: | Institute of Materials Engineering, Australian Nuclear Science and Technology Organisation, Menai, NSW 2234, Australia |
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| Abstract: | The leachability in water of metakaolin based geopolymers with molar ratios of Na/Al = 1 and Si/Al = 1.5-4.0 has been investigated in order to optimise the composition for the immobilisation of nuclear waste. Formulations with Si/Al of around 2 are the most suitable using the ASTM/PCT leach test method. The variability of the leach results is discussed with reference to the microstructure, compressive strength and the degree of polymerisation of the geopolymers as observed here by solid state nuclear magnetic resonance, XRD and infrared measurements. |
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