A new molecularly imprinted polymer prepared by surface imprinting technique for selective adsorption towards kaempferol |
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Authors: | Minqiang He Minjia Meng Jincheng Wan Juan He Yongsheng Yan |
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Affiliation: | (1) School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang, Jiangsu, 212013, People’s Republic of China |
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Abstract: | A new molecularly imprinted polymer (KAE-MPS/SiO2) with high performance for recognizing kaempferol (KAE) was prepared by adopting the surface molecular imprinting technique
with silica nanoparticles modified with 3-methacryloxypropyltrimethoxysilane (MPS) as a carrier material, 2-vinylpridine as
the functional monomer and ethylene glycol dimethacrylate as the crosslinker. The static adsorption experiments indicated
that KAE-MPS/SiO2 had significantly higher adsorption capacity for KAE than its non-imprinted polymers. Scatchard analysis revealed that two
classes of binding sites were formed in KAE-MPS/SiO2 with dissociation constants of 0.26 and 2.34 μmol/mL, and the maximum apparent binding capacity was 3.33 and 16.16 μmol/g,
respectively. The selectivity coefficients of KAE-MPS/SiO2 for KAE in relation to competition species myricetin and chlorogenic acid were 2.51 and 4.24, respectively, which suggested
that KAE-MPS/SiO2 had high recognition selectivity and binding affinity for the template KAE. Dynamic binding study showed that the KAE-MPS/SiO2 had good site accessibility and mass transport for KAE. The KAE-MPS/SiO2 can be reused many times without decreasing their adsorption capacities significantly. |
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