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Mg-Zn-Si体系的相平衡计算及应用
引用本文:赵阳子,赵云鹤,李 谦,陈双林,张捷宇,周国治.Mg-Zn-Si体系的相平衡计算及应用[J].稀有金属材料与工程,2010,39(8):1385-1389.
作者姓名:赵阳子  赵云鹤  李 谦  陈双林  张捷宇  周国治
作者单位:1. 上海大学,上海市现代冶金及材料制备重点实验室,上海,200072
2. 上海大学,上海市现代冶金及材料制备重点实验室,上海,200072;Compu Therm,LLC,Madison,WI 53719,USA
3. 上海大学,上海市现代冶金及材料制备重点实验室,上海,200072;北京科技大学,北京,100083
基金项目:国家科技支撑计划,贵州省"十一五"重大专项,中国铝业公司科技发展基金 
摘    要:利用Calphad方法重新评估了Mg-Si二元系的液相,并结合Mg-Zn和Zn-Si二元系热力学数据,外推得到Mg-Zn-Si三元系热力学参数;同时根据Mg2Si-MgZn2伪二元相图实验数据评估了Mg-Zn-Si系的液相三元相交互作用参数,计算相图与实验数据较一致。利用Scheil凝固模型模拟了Mg-2.33Zn-0.9Si(at%)合金的凝固过程,预测了镁合金在铸造冷却过程中的相演变信息,模拟计算结果与实验结果吻合较好

关 键 词:Mg-Zn-Si系  热力学计算  相图计算  凝固
收稿时间:2009/8/27 0:00:00

Thermodynamic Calculation of Phase Equilibria in the Mg-Zn-Si System and Its Application
Zhao Yangzi,Zhao Yunhe,Li Qian,Chen Shuanglin,Zhang Jieyu and Zhou Guozhi.Thermodynamic Calculation of Phase Equilibria in the Mg-Zn-Si System and Its Application[J].Rare Metal Materials and Engineering,2010,39(8):1385-1389.
Authors:Zhao Yangzi  Zhao Yunhe  Li Qian  Chen Shuanglin  Zhang Jieyu and Zhou Guozhi
Affiliation:Shanghai Key Laboratory of Modern Metallurgy & Materials Processing, Shanghai University, Shanghai 200072, China
Abstract:The liquid phase of the Mg-Si binary system was re-assessed by the Calphad approach. Combined the thermodynamic data of Mg-Zn and Zn-Si binary systems, the thermodynamic parameters of Mg-Zn-Si ternary system were obtained by extrapolation. Based on the phase diagram of Mg2Si-MgZn2 pseudo-binary system, the liquid ternary interaction parameters of Mg-Zn-Si system were assessed. The results show that the calculated phase diagram agrees basically with the experimental data. The solidification process of the Mg-2.33Zn-0.9Si (at%) alloy was simulated by Scheil model, and the phase evolution of Mg alloy during cooling casting was predicted. The results agree with the previous experiment results
Keywords:Mg-Zn-Si system  thermodynamic calculation  phase diagram calculation  solidification
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