Spectroscopic study of nitrogen doping of multi-walled carbon nanotubes |
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Authors: | Enouz S Bantignies J L Babaa M R Alvarez L Parent P Le Normand F Stéphan O Poncharal P Loiseau A Doyle B P |
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Affiliation: | Laboratoire des Collo?des Verres et Nanomatériaux, Université Montpellier II, cc026, Place Eugène Bataillon, 34095 Montpellier, France. |
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Abstract: | Combined spatially resolved electron-energy loss spectroscopy (EELS) and high resolution near-edge X-ray absorption fine structure (NEXAFS) spectroscopy have been used to investigate the nitrogen doping of multi-walled carbon nanotubes (N-MWNT). EELS indicates that most of the tubes are nitrogen-doped. NEXAFS spectroscopy reveals pyridine-like and nitrile N structures. High resolution NEXAFS experiments show that the main nitrogen concentration originates from a high amount of molecular N2 encapsulated into only a small quantity of tubes. |
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