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Thermal Modulation of Nanomotor Movement
Authors:Shankar Balasubramanian  Daniel Kagan  Kalayil Manian Manesh  Percy Calvo‐Marzal  Gerd‐Uwe Flechsig  Joseph Wang
Affiliation:1. Department of Nanoengineering University of California, San Diego La Jolla, CA 92093 (USA);2. University of Rostock, Department of Chemistry D‐18051 Rostock (Germany)
Abstract:Motion control is essential for various applications of man‐made nanomachines. The ability to control and regulate the movement of catalytic nanowire motors is illustrated by applying short heat pulses that allow the motors to be accelerated or slowed down. The accelerated motion observed during the heat pulses is attributed primarily to the thermal activation of the redox reactions of the H2O2 fuel at the Pt and Au segments and to the decreased viscosity of the aqueous medium at elevated temperatures. The thermally modulated motion during repetitive temperature on/off cycles is highly reversible and fast, with speeds of 14 and 45 µm s?1 at 25 and 65 °C, respectively. A wide range of speeds can be generated by tailoring the temperature to yield a linear speed–temperature dependence. Through the use of nickel‐containing nanomotors, the ability to combine the thermally regulated motion of catalytic nanomotors with magnetic guidance is also demonstrated. Such on‐demand control of the movement of nanowire motors holds great promise for complex operations of future manmade nanomachines and for creating more sophisticated nanomotors.
Keywords:catalytic nanowires  nanomachines  nanomotors  hydrogen peroxide  temperature modulation
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