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Luminescence investigation of Eu~(3+)-Bi~(3+) co-doped CaMoO_4 phosphor
引用本文:康逢文,胡义华,吴浩怡,居桂方,牟中飞,李娜娜. Luminescence investigation of Eu~(3+)-Bi~(3+) co-doped CaMoO_4 phosphor[J]. 中国稀土学报(英文版), 2011, 29(9): 837-842. DOI: 10.1016/S1002-0721(10)60552-2
作者姓名:康逢文  胡义华  吴浩怡  居桂方  牟中飞  李娜娜
作者单位:School of Physics and Optoelectronic Engineering, Guangdong University of Technology, Guangzhou 510006, China
基金项目:Project supported by the National Natural Science Foundation of China (21071034)
摘    要:


关 键 词:光致发光性能  红色荧光粉  欧盟  X射线衍射  晶体结构  激发光谱  能量转移  红色发光
收稿时间:2011-04-07

Luminescence investigation of Eu-Bi co-doped CaMoO4 phosphor
Fengwen KANG,Yihua HU,Haoyi WU,Guifang JU,Zhongfei MU,Nana LI. Luminescence investigation of Eu-Bi co-doped CaMoO4 phosphor[J]. Journal of Rare Earths, 2011, 29(9): 837-842. DOI: 10.1016/S1002-0721(10)60552-2
Authors:Fengwen KANG  Yihua HU  Haoyi WU  Guifang JU  Zhongfei MU  Nana LI
Affiliation:(School of Physics and Optoelectronic Engineering, Guangdong University of Technology, Guangzhou 510006, China)
Abstract:
A series of Eu3+-Bi3+ co-doped CaMoO4 red phosphors were synthesized via the solid-sate reaction method. The crystal structures of the obtained samples were identified by X-ray powder diffraction (XRD). The photoluminescence property was investigated, and the results showed that the intensity of excitation spectra and emission spectra could be changed with different doping ratios of Bi3+/Eu3+. The proposed explanation of these changes was from the energy transfer between Bi3+ and Eu3+ and the unbalanced charge from the substitution of Eu3+ and Bi3+ for Ca2+ in CaMoO4. The obtained samples are a promising red light emitting phosphor for the needs of different excitation sources with near-UV and blue GaN-based chips.
Keywords:solid-state reaction   red phosphor   Eu3+   Bi3+   MoO4   rare earths
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