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Structure characteristics and electrochemical properties of LiMn2O4 modified by LiCoO2
引用本文:ZhenpingCai MingxunLi ShigangLu WeihuaJin. Structure characteristics and electrochemical properties of LiMn2O4 modified by LiCoO2[J]. 北京科技大学学报(英文版), 2005, 12(3): 274-276
作者姓名:ZhenpingCai MingxunLi ShigangLu WeihuaJin
作者单位:GeneralResearchInstituteofNon-ferrousMetals.Beijing100088,China
摘    要:In order to improve the cycle performance of LiMn2O4, the modified LiMn2O4 was prepared by solid-state reactions using LiMn2O4 and LiCoO2 as precursors. XRD and EDS were used to study the structure properties of the modified LiMn2O4. The electrochemical properties of the modified LiMn2O4 were also investigated, The results show that Li and Co atoms could insert into the LiMn2O4 crystal lattice and a newly formed spinel phase, modified LiMn2O4 was obtained. The modified LiMn2O4 exhibits excellent cycle ability at room and elevated temperatures compared to pure LiMn2O4. The improved electrochemical stability of the modified LiMn2O4 attributes to the entrance of Li and Co ions inserted into the spinel crystal structure.

关 键 词:锂离子电池 尖晶石 LiMn2O4 电化学性质 结构特征

Structure characteristics and electrochemical properties of LiMn2O4 modified by LiCoO2
Zhenping Cai,Mingxun Li,Shigang Lu,Weihua Jin. Structure characteristics and electrochemical properties of LiMn2O4 modified by LiCoO2[J]. Journal of University of Science and Technology Beijing, 2005, 12(3): 274-276
Authors:Zhenping Cai  Mingxun Li  Shigang Lu  Weihua Jin
Abstract:In order to improve the cycle performance of LiMn2O4, the modified LiMn,O4 was prepared by solid-state reactions using LiMn2O4 and LiCoO2 as precursors. XRD and EDS were used to study the structure properties of the modified LiMn2O4. The electrochemical properties of the modified LiMn2O4 were also investigated. The results show that Li and Co atoms could insert into the LiMn2O4crystal lattice and a newly formed spinel phase, modified LiMn2O4 was obtained. The modified LiMn2O4 exhibits excellent cycle ability at room and elevated temperatures compared to pure LiMn2O4. The improved electrochemical stability of the modified LiMn2O4 attributes to the entrance of Li and Co ions inserted into the spinel crystal structure.
Keywords:lithium ion battery  spinel LiMn2O4  modification  LiCoO2
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