Electrochemical performance study of proton exchange membrane electrolyzer considering the effect of bubble coverage |
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| Affiliation: | 1. School of Electrical and Mechanical Engineering, Xinjiang Agricultural University, Urumqi, 830023, China;2. Key Laboratory of Hydrogen Energy Utilization Technology, Xinjiang Institute of Engineering, Urumqi, 830023, China;3. School of Electrical Engineering, Xinjiang University, Urumqi, 830023, China;1. New Energy Materials Research Center, College of Materials and Environmental Engineering, Hangzhou Dianzi University, Hangzhou 310018, PR China;2. School of Materials Science and Engineering, Zhejiang University, Hangzhou 310027, PR China;3. Shanghai Synchrotron Radiation Facility, Shanghai Advanced Research Institute, Chinese Academy of Sciences, Shanghai 201203, PR China;1. School of Rare Earths, University of Science and Technology of China, Hefei, 230026, PR China;2. Ganjiang Innovation Academy, Chinese Academy of Sciences, Ganzhou, 341000, PR China;3. Key Laboratory of Advanced Fuel Cells and Electrolyzers Technology of Zhejiang Province, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo, Zhejiang, 315201, PR China;4. Guangzhou Power Supply Bureau, Guangdong Power Grid Co., Ltd., No. 2 of Tianhe nan 2nd Rd, Guangzhou, Guangdong Province, 510620, PR China;1. College of Materials Science and Engineering, Qingdao University of Science and Technology, No. 53 Zhengzhou Road, Qingdao 266042, China;2. College of Electromechanical Engineering, Qingdao University of Science and Technology, No. 53 Zhengzhou Road, Qingdao 266042, China;1. Department of Mechanical Engineering of Yuan Ze University ChungeLi District, Taoyuan City, Taiwan;2. Department of Mechanical Engineering /Fuel Cell Centre, Yuan Ze University, ChungeLi District, Taoyuan City, Taiwan |
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| Abstract: | Bubble dynamics are closely related to the electrochemical performance of a proton exchange membrane electrolyzer (PEMEC). However, tiny bubbles need to be clustered together to affect the electrochemical performance of PEMEC significantly. In this paper, the effect of microscopic bubbles on macroscopic electrochemical properties were assessed by bubble coverage. The bubble dynamics, two-phase flow, and electrochemical performance were captured under different conditions using a high-speed, microscopic visualization experimental system. The results show that various factors influence the two-phase flow pattern. At 60 °C, 1.5 A/cm2 and 5 mL/min, the annular flow occupied 76.8% of the gas phase area, and when the water flow increased to 80 mL/min, the annular flow ratio decreased substantially to 2.7%. The two-phase flow of bubbles in the flow channel showed different flow patterns over time. Under the experimental conditions (60 °C, 20 mL/min, 0.8 A/cm2), the bubble flow pattern experienced the emergence of bubbles, bubble flow, segmental plug flow, annular flow, and final steady state with the occurrence times of 0.15 s, 1.5 s, 5.0 s, 10.5 s, and 21.2 s, respectively. The bubble coverage increased with current density and temperature, while it decreased with the increase of water velocity. In addition, the effects of temperature and water velocity on bubble coverage and PEMEC performance vary in principle. Specifically, higher temperature mainly improves the bubble coverage by increasing the electrochemical performance of PEMEC. In contrast, higher water velocity mainly improves the electrochemical performance of PEMEC by decreasing the bubble coverage. This study elucidates the relationship between microscopic bubbles and macroscopic electrochemical performance, contributing to a better understanding of the processes and principles of bubble effects on the electrochemical performance of PEMEC. The results may provide a theoretical basis and experimental data for operating condition optimization, operating efficiency improvement, multiphase flow study, gas diffusion layer structure, and flow field design of PEMEC. |
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| Keywords: | PEM electrolyzer Bubble dynamics Two-phase flow Visualization Hydrogen energy |
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