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| 氟代聚丙烯酸酯的合成与膜形貌及疏水性能 | |
| 引用本文： | 安秋凤,袁俊敏,王前进,付永山,贾顺田. 氟代聚丙烯酸酯的合成与膜形貌及疏水性能[J]. 高分子材料科学与工程, 2011, 0(2): 16-18,22 |
| 作者姓名： | 安秋凤 袁俊敏 王前进 付永山 贾顺田 |
| 作者单位： | 浙江温州轻工研究院; |
| 基金项目： | 浙江省重大科技专项(优先主题)工业项目(2008C11113); 教育部博士点基金项目(200807080002); 温州市工业科技研究开发项目(G20090071) |
| 摘 要： | 在过氧化苯甲酰作用下,利用甲基丙烯酸十二氟庚酯与丙烯酸丁酯、甲基丙烯酸二甲氨乙酯、丙烯酸羟丙酯的溶液聚合反应合成了一种氟代聚丙烯酸酯(FBDH),用场发射扫描电镜(FESEM)、原子力显微镜(AFM)等对其结构、成膜性及膜形貌进行了研究.结果表明,在观察尺寸为50 nm、扫描范围为5 μm×5μm条件下,观察所合成的F... |
| 关 键 词： | 氟代聚丙烯酸酯 防水 棉织物 形貌 |
Synthesis,Morphology and Hydrophobicity of Fluorinated Polyacrylate |
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| Qiufeng An,Junmin Yuan,Qianjin Wang,Yongshan Fu,Shuntian Jia. Synthesis,Morphology and Hydrophobicity of Fluorinated Polyacrylate[J]. Polymer Materials Science & Engineering, 2011, 0(2): 16-18,22 | |
| Authors: | Qiufeng An Junmin Yuan Qianjin Wang Yongshan Fu Shuntian Jia |
| Affiliation: | Qiufeng An,Junmin Yuan,Qianjin Wang,Yongshan Fu,Shuntian Jia(Faculty of Wenzhou Light Industry,Wenzhou 325003,China) |
| Abstract: | In the presence of benzoyl peroxide as an initiator,a fluorinated polyacrylate (FBDH) was synthesized by copolymerization of dodecafluoroheptyl methacrylate(RfAA),butyl acrylate(BA),dimethylaminoethyl methacrylate(DM) and 2-hydroxypropyl acrylate(HPAA) in tertiary butanol solution.Chemical structure of FBDH was characterized by infrared spectrum(IR) and 1H nuclear magnetic resonance spectrum(1H-NMR),then film morphology and performance of FBDH on different substrates were investigated by FESEM,atomic force ... |
| Keywords: | fluorinated polyacrylate hydrophobicity cotton fabric film morphology |
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