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The direct adsorption of low concentration gallium from fly ash
Authors:Shaopeng Li  Wenfen Wu  Xinjuan Hou
Affiliation:1. Key Laboratory of Green Process and Engineering, National Engineering Laboratory for Hydrometallurgical Cleaner Production Technology, Institute of Process Engineering, Chinese Academy of Sciences, Beijing, P. R. China;2. University of Chinese Academy of Sciences, Beijing, P. R. China
Abstract:This study is mainly focused on the direct adsorption of low concentration gallium from the feed solution in pre-desilication soda-lime sintering process from coal fly ash. The adsorption kinetics, mechanism, and the influence of impurities, cyclic times, and eluant content are systematically researched. Results showed that the adsorption capacity was 2.89 mg/g resin with gallium concentration of 50 mg/L. The adsorption mechanism could be explained by the interaction between the oxygen atoms and nitrogen atoms of amidoxime group. Gallium was eluted efficiently by NaOH and Na2S mixed solution and the concentration could be reached to 2400 mg/L.
Keywords:Gallium  coal fly ash  amidoxime resin  adsorption
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