| 1-对甲氧基苯基-cis-1,2-环己二醇的合成 |
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| 引用本文： | 张颂培,侯宏森,陈娟.1-对甲氧基苯基-cis-1,2-环己二醇的合成[J].化学试剂,2006,28(2):95-97. |
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| 作者姓名： | 张颂培 侯宏森 陈娟 |
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| 作者单位： | 北京工商大学,化工学院,北京,100037 |
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| 摘 要： | 利用对甲氧基苯基溴化镁和环己酮首先在冰水浴控温下开始反应,接着回流40min制得α-位取代的环己醇,用对甲苯磺酸脱水后纯化得到1-对甲氧基苯基-1,2-环己烯,再于冰水浴中用甲酸-过氧化氢氧化环己烯,经水解制得标题化合物,总收率34%。
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| 关 键 词： | 1-对甲氧基苯基-cis-1 2-环己二醇 合成 表征 |
| 文章编号： | 0258-3283（2006）02-0095-03 |
| 收稿时间： | 2005-06-18 |
| 修稿时间： | 2005-06-18 |
Synthesis and characteristic of 1-p-methoxyphenyl-cis-cyclohexane-1,2-diols |
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| ZHANG Song-pei,HOU Hong-sen,CHEN Juan.Synthesis and characteristic of 1-p-methoxyphenyl-cis-cyclohexane-1,2-diols[J].Chemical Reagents,2006,28(2):95-97. |
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| Authors: | ZHANG Song-pei HOU Hong-sen CHEN Juan |
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| Affiliation: | College of Chemical and Environmental Engineering, Beijing Technology and Business University, Beijing 100037, China |
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| Abstract: | 1-p-Methoxyphenyl-cyclohexanol was prepared by the reaction of Grignard reagent with cyclohexanone followed with dehydration to give 1-p-methoxyphenyl-1,2-cyclohexene.1-p-methoxyphenyl-cis-cyclohexane-diol-1,2 can be obtained by the oxidation reaction of 1-pmethoxyphenyl-cyclohexene with hydrogen peroxide.The total yield is 34%. |
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| Keywords: | 1-p-methoxyphenyl-cis-1 2-cyclohexanediol synthesis characterization |
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