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新型含氟甾体类液晶的合成与相变研究
引用本文:刘克刚,李衡峰,沈悦海,王侃,闻建勋.新型含氟甾体类液晶的合成与相变研究[J].液晶与显示,2001,16(3):181-187.
作者姓名:刘克刚  李衡峰  沈悦海  王侃  闻建勋
作者单位:中国科学院上海有机化学研究所上海 200032 E-mail:Wenjianxun@pub.sioc.ac.cn
基金项目:国家自然科学基金资助(2997403
摘    要:设计并合成了3个系列的侧位氟原子取代的甾类液晶,其相变行为通过偏光显微镜观察和DSC进行验证,可以发现氟原子的取代位置不同,对化合物的相变性质影响很大。

关 键 词:液晶  铁电性  近晶相  氟甾体  合成  相变性质
文章编号:1007-2780(2001)03-0181-07
修稿时间:2000年12月17

Synthesis and Characteristics of Novel Fluorinated Steroidal Liquid Crystals
LIU Ke-gang,LI Heng-feng,SHEN Yue-hai,WANG Kan,WEN Jian-xun.Synthesis and Characteristics of Novel Fluorinated Steroidal Liquid Crystals[J].Chinese Journal of Liquid Crystals and Displays,2001,16(3):181-187.
Authors:LIU Ke-gang  LI Heng-feng  SHEN Yue-hai  WANG Kan  WEN Jian-xun
Abstract:Three series of fluorinated steroidal liquid crystals were synthesized. The mesomorphic behaviors of the compounds were characterized by differential scanning calorimetry (DSC) and optical polarization microscopy (POM). Two series of the compounds A and compounds C exhibit a cholesteric phase only, and the series of compounds B exhibit a smectic A and a cholesteric phase. The relationship between the structure and the properties is discussed in detail.
Keywords:liquid crystals  ferroelectrics  smectic phase
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