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有机小分子掺杂的聚合物共混发光二极管
引用本文:黄劲松,杨开霞,谢志元,李传南,侯晶莹,高强,马於光,沈家骢,刘式墉. 有机小分子掺杂的聚合物共混发光二极管[J]. 液晶与显示, 1999, 14(1): 18-22
作者姓名:黄劲松  杨开霞  谢志元  李传南  侯晶莹  高强  马於光  沈家骢  刘式墉
作者单位:1. 吉林大学集成光电子学国家联合重点实验室,长春,130023
2. 吉林大学超分子结构与谱学开放实验室,长春,130023
基金项目:国家自然科学基金,中国科学院长春应用化学研究所高分子物理开放实验室资助
摘    要:报道了用可溶性发光材料聚(2,5-二丁氧基苯)做发光材料,分别与母体聚合物聚乙烯基咔唑(PVK)和聚甲基丙烯酸甲脂(PMMA)共混,并掺杂电子传输材料叔丁基联苯基苯基口恶二唑和空穴传输材料二胺衍生物作发光层,用铟锡氧化物和铝分别作正负电极,制作了两种蓝紫光有机/聚合物单层发光器件。通过比较两种器件的器件特性,发现以PMMA做母体的器件比用PVK做母体的器件有更好的稳定性,器件开启电压为10V左右,发光峰值波长均位于424nm,电致发光效率可达2.9%,比用PVK做母体的器件效率高一倍多。

关 键 词:聚合物  共混  发光二极管  电致发光  效率

Organic Light Emitting Diodes Using Doped Polymer Blends
Huang Jinsong,Yang Kaixia,Xie Zhiyuan,Li Chuannan,Hou Jingying,Gao Qiang,Ma Yuguang,Shen Jiacong,Liu Shiyong. Organic Light Emitting Diodes Using Doped Polymer Blends[J]. Chinese Journal of Liquid Crystals and Displays, 1999, 14(1): 18-22
Authors:Huang Jinsong  Yang Kaixia  Xie Zhiyuan  Li Chuannan  Hou Jingying  Gao Qiang  Ma Yuguang  Shen Jiacong  Liu Shiyong
Abstract:Two violet blue electroluminescent(EL) devices are fabricated, which consist of a soluble conjugated polymer poly(2,5 dibutoxyphenylene) as an emitter, poly(N vinycarbazole)(PVK) and poly(methyl methacrylate)(PMMA) as the matrix polymers respectively, and dispersing an organic electron transporting material 2 (4 biphenylyl) 5 (4 tert butyl phenyl) 1, 3, 4 oxadiazole and a hole transporing material diamine derivative into the polymer blends ITO serves as the anode and Al as the cathode The results show the turn on voltages and emission peaks of two devices are the same, about 10V and 424nm respectively However, the EL efficiency of the device used PMMA as the matrix reaches to 2 9%, which is one time than that of the device used PVK as the matrix And the stability of the device used PMMA as the matrix is improved
Keywords:polymer blend light emitting diodes electroluminescence efficiency
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