Safe and fast-charging Li-ion battery with long shelf life for power applications |
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Authors: | K. Zaghib M. DontignyA. Guerfi P. CharestI. Rodrigues A. MaugerC.M. Julien |
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Affiliation: | a Institut de Recherche d’Hydro-Québec, Varennes, QC, Canada J3X 1S1 b Institut de Minéralogie et de Physique des Milieux Condensés, Université Pierre et Marie Curie, 140 rue de Lourmel, 75015 Paris, France c Laboratoire de Physicochimie des Electrolytes, Colloïdes et Sciences Analytiques, Université Pierre et Marie Curie, Bat. F, 4 place Jussieu, 75005 Paris, France |
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Abstract: | We report a Li-ion battery that can be charged within few minutes, passes the safety tests, and has a very long shelf life. The active materials are nanoparticles of LiFePO4 (LFP) and Li4Ti5O12 (LTO) for the positive and negative electrodes, respectively. The LiFePO4 particles are covered with 2 wt.% carbon to optimize the electrical conductivity, but not the Li4Ti5O12 particles. The electrolyte is the usual carbonate solvent. The binder is a water-soluble elastomer. The “18650” battery prepared under such conditions delivers a capacity of 800 mAh. It retains full capacity after 20,000 cycles performed at charge rate 10C (6 min), discharge rate 5C (12 min), and retains 95% capacity after 30,000 cycles at charge rate 15C (4 mn) and discharge rate 5C both at 100% DOD and 100% SOC. |
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Keywords: | Li-ion batteries Olivines Titanates |
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