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Roles of Eu^2+, Dy^3+ Ions in Persistent Luminescence of Strontium Aluminates Phosphors
引用本文:吕兴栋. Roles of Eu^2+, Dy^3+ Ions in Persistent Luminescence of Strontium Aluminates Phosphors[J]. 武汉理工大学学报(材料科学英文版), 2008, 23(5): 652-657. DOI: 10.1007/s11595-007-5652-7
作者姓名:吕兴栋
作者单位:Academy of Functional Materials, Jiangxi University of Finance and Economy, Nanchang 330013, China
基金项目:Funded by Jiangxi University of Finance and Economy and Jlangxi Provincial Department of Education (No.[2007]260)
摘    要:The polycrystalline Eu^2+ and Dy ^3+ co-doped strontium aluminates SrAl2O4: Eu^2+, Dy^3+ with different compositions were prepared by solid state reactions. The UV-excited photoluminescence, persistent luminescence and thermo-luminescence were studied and compared. Results show that the doped Eu^2+ ion in SrAl2O4: Eu^2+, Dy^3+ phosphors works as not only the UV-excited luminescent center but also the persistent luminescent center. The doped Dy^3+ ion can hardly yield any luminescence under UV-excitation, but effectively enhance the persistent luminescence and thermo-luminescence of SrAl2O4: Eu^2+. Dy^3+ co-doping can help form electron traps with appropriate depth due to its suitable electro-negativity, and increase the density and depth of electron traps. Based on above observations, a persistent luminescence mechanism, electron transfer model, is proposed and illustrated.

关 键 词:铝酸锶  磷光体  持续发光  稀土金属    
收稿时间:2006-06-04

Roles of Eu2+, Dy3+ ions in persistent luminescence of strontium aluminates phosphors
Lü Xingdong,Minjuan Zhong,Renqin Wang. Roles of Eu2+, Dy3+ ions in persistent luminescence of strontium aluminates phosphors[J]. Journal of Wuhan University of Technology. Materials Science Edition, 2008, 23(5): 652-657. DOI: 10.1007/s11595-007-5652-7
Authors:Lü Xingdong  Minjuan Zhong  Renqin Wang
Affiliation:(1) Academy of Functional Materials, Jiangxi University of Finance and Economy, Nanchang, 330013, China
Abstract:The polycrystalline Eu2+ and Dy3+ co-doped strontium aluminates SrAl2O4: Eu2+, Dy3+ with different compositions were prepared by solid state reactions. The UV-excited photoluminescence, persistent luminescence and thermo-luminescence were studied and compared. Results show that the doped Eu2+ ion in SrAl2O4: Eu2+, Dy3+ phosphors works as not only the UV-excited luminescent center but also the persistent luminescent center. The doped Dy3+ ion can hardly yield any luminescence under UV-excitation, but effectively enhance the persistent luminescence and thermo-luminescence of SrAl2O4: Eu2+. Dy3+ co-doping can help form electron traps with appropriate depth due to its suitable electro-negativity, and increase the density and depth of electron traps. Based on above observations, a persistent luminescence mechanism, electron transfer model, is proposed and illustrated. Funded by Jiangxi University of Finance and Economy and Jiangxi Provincial Department of Education (No.[2007]260)
Keywords:strontium aluminate  persistent luminescence  thermo-luminescence  rare earth ion
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