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The Facile Synthesis and Energetic Properties of an Energetic Furoxan Lacking Traditional “Explosophore” Moieties: (E,E)‐3,4‐bis(oximomethyl)furoxan (DPX1)
Authors:Thomas M. Klapö  tke,Davin G. Piercey,Joerg Stierstorfer
Abstract:
Energetic furoxan (E,E)‐3,4‐bis(oximomethyl)furoxan (DPX1) was synthesized in 75 % yield, using a literature procedure, from a precursor readily available in one step from nitromethane. DPX1 was characterized for the first time as an energetic material in terms of calculated performance (Vdet = 8245 m s−1; pCJ = 29.0 GPa) and measured sensitivity (impact: 10 J; friction: 192 N; Tdec: 168 °C). DPX1 exhibits a sensitivity less than that of RDX, and a performance significantly higher than 2,4,6‐trinitrotoluene (TNT).
Keywords:Energetic Materials  Furoxan  Oxime  X‐ray
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