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有机硅氧烷/丙烯酸酯乳液的无皂共聚合研究
引用本文:王国建.有机硅氧烷/丙烯酸酯乳液的无皂共聚合研究[J].建筑材料学报,2002,5(3):269-273.
作者姓名:王国建
作者单位:同济大学材料科学与工程学院,上海,200092
摘    要:采用表面活性单体烯丙基-2-羟丙基醚磺酸钠(NaAPS)和丙烯酸聚羟基丙酸酯(PHPA)作为乳化体系进行无皂硅氧烷/丙烯酸酯(硅丙)共聚乳液的制备,研究了表面活性单体种类,共用和用量对硅丙共聚乳液及其涂料性能的影响。结果表明,与普通硅丙共聚乳液相比,无皂硅丙共聚乳液涂料的涂膜有较好的综合性能。

关 键 词:无皂乳液聚合  有机硅  聚合物  丙烯酸酯乳液
文章编号:1007-9629(2002)03-0269-05
修稿时间:2001年10月22

Preparation of Siloxane/Acrylate Copolymeric Emulsion by a Soap-free Emulsion Polymerization
WANG Guo-jian.Preparation of Siloxane/Acrylate Copolymeric Emulsion by a Soap-free Emulsion Polymerization[J].Journal of Building Materials,2002,5(3):269-273.
Authors:WANG Guo-jian
Abstract:The soap-free siloxane/acrylate copolymeric emulsion was prepared by using sodium allyl-2-hydroxy propyl ether sulfonate(NaAPS) and poly(hydroxy propionic acid) acrylate(PHPA) as emulsifying system. The influence of types, cooperation and contents of surface-active monomers on the properties of soap-free siloxane/acrylate copolymeric emulsion and its coating were studied. The results show that the coating of the soap-free siloxane/acrylate copolymeric emulsion has better comprehensive properties than that of the general siloxane/acrylate emulsion.
Keywords:soap-free emulsion polymerization  polysiloxane  polyacrylate emulsion
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