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The cobalt content effect on the electrochemical behavior of nickel hydroxide electrodes
Authors:M.G. Ortiz  E.B. Castro  S.G. y Real
Affiliation:1. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas (INIFTA), Facultad de Ciencias Exactas, Universidad Nacional de La Plata, C.C.16, Suc. 4, 1900 La Plata, Argentina;2. Facultad Regional La Plata, Universidad Tecnológica Nacional, Calle 60 y 124, La Plata, Argentina
Abstract:In this paper, the study of nickel hydroxide porous electrodes containing different concentrations of cobalt as additive (2–10%), polytetrafluoroethylene (PTFE) as binder material and prepared by chemical impregnation on nickel sintered substrate, are presented. The characterization of the different electrodes is performed using optical techniques such as scanning electron microscopy (SEM), energy dispersive X-ray analysis (EDAX) and electrochemical techniques as cyclic voltammetry, charge-discharge curves and electrochemical impedance spectroscopy (EIS). The results indicate that the concentration of 5% metallic Co improves the electrochemical behavior of the active material.
Keywords:Cathode in alkaline batteries   Nickel hydroxide   Metallic cobalt   Porous electrodes
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