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Effect of YO1.5 Dopant on Unit-Cell Parameters of ZrO2 at Low Contents of YO1.5
Authors:Hideo Toraya
Affiliation:Ceramic Engineering Research Laboratory, Nagoya Institute of Technology, Asahigaoka, Tajimi 507, Japan
Abstract:
The effect of YO1.5 dopant on unit-cell parameters of ZrO2 (YO1.5=0 to 14.6 mol%) were examined by the X-ray whole-powder-pattern decom-position technique. The unit cell of monoclinic ZrO2 has the largest expansion along the direction perpen-dicular to (100). The rate of increase of the unit-cell volume of monoclinic ZrO2 with YO1.5 content is greater than that of tetragonal ZrO2 and comparable to that of cubic ZrO2.
Keywords:zirconia    yttria    crystallography    phase transformations    dopants
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