| 硫酸氢钠催化合成丁酸正丁酯 |
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| 引用本文： | 俞善信,文瑞明,雷存喜.硫酸氢钠催化合成丁酸正丁酯[J].精细石油化工进展,2002,3(2):36-37. |
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| 作者姓名： | 俞善信 文瑞明 雷存喜 |
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| 作者单位： | 益阳师范高等专科学校化学系,益阳,413049 |
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| 摘 要： | 硫酸氢钠能代替硫酸用于酯化作用中。在硫酸氢钠存在下,由丁酸和正丁醇合成了丁酸正丁酯。当丁酸、正丁醇和硫酸氢钠的质量比为1:1.25:0.036时,回流分水45 min,酯收率达93.7％。研究了催化剂的重复使用情况。
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| 关 键 词： | 丁酸正丁酯 合成 硫酸氢钠 催化 |
| 修稿时间： | 2001年11月30 |
Synthesis of n-Butyl Butyrate by Catalysis of Sodium Bisulfate |
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| Yu Shanxin Wen Ruiming Lei Cunxi.Synthesis of n-Butyl Butyrate by Catalysis of Sodium Bisulfate[J].Advances in Fine Petrochemicals,2002,3(2):36-37. |
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| Authors: | Yu Shanxin Wen Ruiming Lei Cunxi |
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| Abstract: | Sodium bisulfate can be used as catalyst for the esterification instead of sulphuric acid. n - Butyl bu-tyrate was synthesized from butyric acid and n - butyl alcohol in the presence of sodium bisulfate monohydrate. The yield of the ester was up to 93.7 % under mass ratio of butyric acid, n - butyl alcohol, and sodium bisulfate of 1:1 .25 :0.036, refluxing and water segregating for 45 min. The reusability of the catalyst was studied. |
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| Keywords: | n - butyl butyrate synthesis sodium bisulfate catalysis |
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