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核-壳结构的沸石分子筛复合材料研究进展
引用本文:薛招腾,唐雪婷,王文兴,赵东元.核-壳结构的沸石分子筛复合材料研究进展[J].石油学报(石油加工),2015,31(2):228-243.
作者姓名:薛招腾  唐雪婷  王文兴  赵东元
作者单位:复旦大学 化学系 先进材料实验室,上海 200438
基金项目:国家重点基础研究发展计划“973”项目(2012CB224805和2013CB934104)资助和中国博士后科学基金项目(2013M531115)、上海市 博士后基金项目(13R21410400)
摘    要:核-壳结构沸石分子筛复合材料在煤化工、石油化工、精细化工等领域展现了优异的性能。概述了核-壳结构沸石分子筛复合材料的制备及其应用。根据核-壳结构复合材料核和壳的组成,可以分为沸石为核型、沸石为壳型及全沸石型核-壳结构复合材料3类。同时介绍了具有特殊核-壳结构的空心沸石、磁性沸石的构建,并展望了核-壳结构沸石分子筛复合材料的发展及应用前景。

关 键 词:沸石  核-壳结构  介孔材料  蛋黄-蛋壳结构  磁性沸石  空心沸石  合成  催化  
收稿时间:2014-12-02

Review on the Progress of Core-Shell Structured Zeolite Molecular Sieve Materials
XUE Zhaoteng,TANG Xueting,WANG Wenxing,ZHAO Dongyuan.Review on the Progress of Core-Shell Structured Zeolite Molecular Sieve Materials[J].Acta Petrolei Sinica (Petroleum Processing Section),2015,31(2):228-243.
Authors:XUE Zhaoteng  TANG Xueting  WANG Wenxing  ZHAO Dongyuan
Affiliation:Laboratory of Advanced Materials, Department of Chemistry, Fudan University, Shanghai 200438, China
Abstract:The unique zeolite-based core-shell structures showed excellent performance in the coal chemical, petrochemical and fine chemical industries. The synthesis and applications of core-shell structured zeolite composite materials were systematically reviewed. Three core-shell structures for the zeolite composite materials were involved, including zeolite-based crystal as cores, zeolite-based materials as the shells and zeolites@zeolites core-shell structures. The hollow zeolite crystals and the magnetic@zeolites core-shell composites were also mentioned as two kinds of distinguished core-shell structured zeolite composites. The development and application prospects of zeolite-based core-shell structure composite materials were also discussed.
Keywords:zeolites  core-shell structures  mesoporous materials  yolk-shell structures  magnetic zeolites  hollow zeolite  synthesis  catalysis
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