| 硫、磷系添加剂作用机理的研究 |
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| 引用本文： | 乔玉林,方学敬,党鸿辛.硫、磷系添加剂作用机理的研究[J].北京石油化工学院学报,1994(2). |
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| 作者姓名： | 乔玉林 方学敬 党鸿辛 |
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| 作者单位： | 北京燕山石化公司炼油厂研究所，中国科学院兰州化学物理研究所固体润滑开放研究实验室，中国科学院兰州化学物理研究所固体润滑开放研究实验室 北京 102503，兰州730000，兰州730000 |
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| 摘 要： | 对硫、磷系添加剂的相互作用进行了研究,并用HQ-1型摩擦磨损试验机考察了其复配对润滑油抗磨极压性的影响。结果表明:硫、磷系添加剂复配,在一定的摩尔比范围内,抗磨极压性具有协同效应,摩擦表面生成含硫化铁和磷化铁为主体的化学保护膜,并发现T321与T304在一定反应条件下,生成新的含磷化合物。
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| 关 键 词： | 抗磨极压添加剂 润滑油 机理 |
Study on the Mechanism of Sulfur and Phosphorous Series Additives |
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| Qiao Yulin.Study on the Mechanism of Sulfur and Phosphorous Series Additives[J].Journal of Beijing Institute of Petro-Chemical Technology,1994(2). |
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| Authors: | Qiao Yulin |
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| Abstract: | The interaction between sulfur and phosphorous additives was studied by 31P NMR N FT-IR and X-Ray Photoelectron Spectroscopy (XPS) analyses. Lubricating features of combination of sulfur and phosphorous additives were determined by HQ-1 machine, The results indicated the combination of sulfur and phosphorous additives within certain P/S mole ratio have synergistic effects. The reaction film containing iron phosphate and iron sulfide was formed on rubbed surface. A new P-containing compound produced from Sulfurized Olefin (T321) and Dibutylphosphite(T304). |
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| Keywords: | Extreme-Pressure and antiwear additives Lube oil Mechanism |
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