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| Synthesis and Thermoelectric Properties of Ca2.6Nd0.4 Co4O9 Compound | |
| 引用本文： | 车平,张艳,薄其兵,冯静,王静平,孟健. Synthesis and Thermoelectric Properties of Ca2.6Nd0.4 Co4O9 Compound[J]. 中国稀土学报(英文版), 2004, 22(1): 165-167 |
| 作者姓名： | 车平 张艳 薄其兵 冯静 王静平 孟健 |
| 作者单位： | Key Laboratory of Rare Earth Chemistry and Physics，Key Laboratory of Rare Earth Chemistry and Physics，Key Laboratory of Rare Earth Chemistry and Physics，Key Laboratory of Rare Earth Chemistry and Physics，Key Laboratory of Rare Earth Chemistry and Physics，Key Laboratory of Rare Earth Chemistry and Physics Changchun Institute of Applied Chemistry，Chinese Academy of Sciences，Changchun 130022，China，Changchun Institute of Applied Chemistry，Chinese Academy of Sciences，Changchun 130022，China，Changchun Institute of Applied Chemistry，Chinese Academy of Sciences，Changchun 130022，China，Changchun Institute of Applied Chemistry，Chinese Academy of Sciences，Changchun 130022，China，Changchun Institute of Applied Chemistry，Chinese Academy of Sciences，Changchun 130022，China，Changchun Institute of Applied Chemistry，Chinese Academy of Sciences，Changchun 130022，China |
| 摘 要： | Atemperaturedifferenceappliedacrossasolidgeneratesanelectromotiveforce ,characterizedbythethermoelectricpowerofthesolid .ThisphenomenonisnamedSeebeckeffect .Metaloxidematerialswithhighthermoelectricpropertiesaregoodcandidatesforappli cationtothermoelectricpowergenerationbecausefig ureofmeritZ ,definedasZ =S2 σ/κwhereS ,σ ,κaretheSeebeckcoefficient ,electricalconductivityandthermalconductivity ,respectively ,canevaluatetheperformanceofthermoelectricmaterials .Severalsystemshavebeeninvesti… |
| 关 键 词： | Ca2.6Nd0.4Co4O9 稀土 热电性能 合成 无机化学 电池 金属氧化物 |
Synthesis and Thermoelectric Properties of Ca2.6Nd0.4Co4O9 Compound |
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| Che Ping,Zhang Ya,Meng Jian. Synthesis and Thermoelectric Properties of Ca2.6Nd0.4Co4O9 Compound[J]. Journal of Rare Earths, 2004, 22(1): 165-167 | |
| Authors: | Che Ping Zhang Ya Meng Jian |
| Abstract: | The layered cobaltite Ca2.6Nd0.4Co4O9 was synthesized by the solid-state reaction. Their crystal structure was determined by the X-ray powder diffraction and CELL program. The prepared Ca2.6Nd0.4Co4O9 compound has the monoclinic symmetry. The electrical conductivity and Seebeck coefficient were measured from room temperature to 700 ℃ in air. Both the properties increase while rising temperature. The thermoelectric power of Ca2.6Nd0.4Co4O9 is about 242.4 μV·K-1. The results imply a promising way to enhance the thermoelectric properties of the layered cobaltite oxides by optimizing their composition and microstructure. |
| Keywords: | inorganic chemistry thermoelectric property layered cobaltite Seebeck coefficient Ca2.6Nd0.4Co4O9 compound rare earths |
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