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原位聚合改性GF/SAN的界面模型及增韧机理研究
引用本文:曾武,应继儒,刘斌,瞿金平.原位聚合改性GF/SAN的界面模型及增韧机理研究[J].塑料科技,2008,36(7).
作者姓名:曾武  应继儒  刘斌  瞿金平
作者单位:1. 华南理工大学聚合物成型加工工程教育部重点实验室,广东,广州,510640
2. 湖北工业大学化学与环境工程学院,湖北,武汉,430068
摘    要:采用原位乳液聚合接枝法改善玻璃纤维(GF)与苯乙烯-丙烯腈共聚物(SAN)之间的界面黏结性能。对GF/SAN复合材料进行了冲击性能测试和微观结构分析,结果表明:原位聚合改性GF与SAN之间有良好的界面黏合力,可以有效地提高SAN的韧性。设计了一种新的界面模型,以解析原位聚合改性的GF与SAN界面的微观结构,并解释了GF/SAN复合材料的增韧机理。

关 键 词:苯乙烯-丙烯腈共聚物  玻璃纤维  改性  界面模型  增韧

Study on Interfacial Model and Toughening Mechanism of GF/SAN Modified by In-situ Polymerization
Zeng wu,Ying Jiru,Liu Bin,Qu jinping.Study on Interfacial Model and Toughening Mechanism of GF/SAN Modified by In-situ Polymerization[J].Plastics Science and Technology,2008,36(7).
Authors:Zeng wu  Ying Jiru  Liu Bin  Qu jinping
Abstract:The in-situ emulsion polymerization technology was adopted to improve the interfacial adhesion between glass fiber(GF) and styrene-acrylonitrile copolymer(SAN).The impact property of GF/SAN composite was tested,and the microstructure of the composite was also analyzed.The results show that:the interfacial adhesion between GF modified by in-situ polymerization and SAN is excellent,modified GF could improve the toughness of SAN efficiently.An interfacial model was designed to explain the interfacial microstructure between modified GF and SAN.The toughening mechanism of GF/SAN composite was also explained.
Keywords:Styrene-acrylonitrile copolymer  Glass fiber  Modification  Interfacial model  Toughening
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