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Shape selectivity as a function of pore size in epoxidation of alkenes with supported titanium catalysts |
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| Authors: | Takashi Tatsumi Makoto Nakamura Kensei Yuasa Hiroo Tominaga |
| Affiliation: | (1) Department of Synthetic Chemistry, Faculty of Engineering, The University of Tokyo, Hongo, 113 Tokyo, Japan |
| Abstract: | Reactant shape selectivity of supported titanium catalysts for epoxidation of cyclohexene and 2-hexene has an excellent correlation with the pore diameter of the catalysts. With titanosilicate the preference to cis isomer epoxidation is small compared to TiO2-SiO2 probably because of the restriction of its diffusion imposed by the zeolite micropore structure. |
| Keywords: | Shape selectivity epoxidation of alkenes titanium catalyst catalyst pore size titanosilicate catalyst |
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