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磁场对Cu-Pb-La过偏晶合金液-液分离的作用
引用本文:张 林,王恩刚,左小伟,赫冀成.磁场对Cu-Pb-La过偏晶合金液-液分离的作用[J].稀有金属材料与工程,2015,44(2):344-348.
作者姓名:张 林  王恩刚  左小伟  赫冀成
作者单位:东北大学材料电磁过程研究教育部重点实验室
基金项目:国家自然科学基金(50901019,51474066);高等学校博士学科点专项科研基金(2012004211008);中央高校基本科研业务费专项资金(N130409001);国家高技术研究发展计划项目(2007AA03Z519);高等学校学科创新引智计划项目(B07015)
摘    要:本实验在Cu-80%Pb过偏晶合金凝固过程中添加稀土元素La,研究不同冷却速度下稀土元素在过偏晶合金凝固制备中的作用,并研究施加磁场对Cu-Pb过偏晶合金液-液分离区凝固组织的影响,探讨了磁场下第二相的迁移和分布规律,为均质偏晶合金制备技术的改进提供参考。结果表明,添加La元素可显著降低Cu-80%Pb凝固组织中的宏观偏析,促进第二相颗粒的均匀分布和细化。较快的冷却速度下添加La元素的作用更加明显,偏析程度显著降低,在此冷速下进一步施加1 T水平方向磁场,Cu-Pb-La合金凝固过程中宏观偏析得到了抑制,富Cu相颗粒弥散,组织分布均匀。

关 键 词:Cu-Pb-La  过偏晶合金  磁场  液-液分离
收稿时间:3/6/2014 12:00:00 AM

Effect of Magnetic Field on Liquid-liquid Separation
Zhang Lin,Wang Engang,Zuo Xiaowei and He Jicheng.Effect of Magnetic Field on Liquid-liquid Separation[J].Rare Metal Materials and Engineering,2015,44(2):344-348.
Authors:Zhang Lin  Wang Engang  Zuo Xiaowei and He Jicheng
Affiliation:Zhang Lin;Wang Engang;Zuo Xiaowei;He Jicheng;Key Laboratory of Electromagnetic Processing of Materials of Ministry of Education, Northeastern University;
Abstract:La element was used in the solidification process of Cu-80%Pb hypermonotectic alloy, and its effect under different cooling rates was discussed. The effect of magnetic field on microstructure of Cu-Pb hypermonotectic alloy in liquid-liquid separation region was studied, and the mechanism of transition and distribution of second phase was discussed. The results show that the addition of La element significantly decrease the macrosegregation in the solidification structure of Cu-80wt%Pb alloy, and promote the homogeneous size distribution and the size refinement of the second phase. The effect of La under a relatively fast cooling rate is more apparent to reduce segregation, and the further imposition of 1 T magnetic field inhibits the macrosegregation in solidified Cu-Pb-La alloys, leading to a homogeneous distribution of dispersed Cu-rich particles.
Keywords:Cu-Pb-La  hypermonotectic alloys  magnetic field  liquid-liquid separation
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