High-Temperature Oxidation Behavior of Ti-22Al-27(Nb, Zr) Alloys |
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Authors: | Dang Wei Li Jinshan Zhang Tiebang and Kou Hongchao |
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Affiliation: | Dang Wei;Li Jinshan;Zhang Tiebang;Kou Hongchao;State Key Laboratory of Solidification Processing, Northwestern Polytechnical University; |
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Abstract: | The oxidation behavior of Ti-22Al-(27-x)Nb-xZr (x=0, 1, 6, at%) was evaluated over a temperature range of 650~800 oC in air. The phase composition and the morphology of the formed scales were investigated by X-ray diffraction and scanning electron microscopy. The results show that the alloys containing Zr exhibit better oxidation resistance than Ti-22Al-27Nb alloy. The main oxidation product is TiO2 for all the alloys oxidized at 650 oC for 100 h. A mixture of TiO2, Al2O3 and AlNbO4 is formed for Ti-22Al-27Nb and Ti-22Al-26Nb-1Zr oxidized at 800 oC for 100 h; however, ZrO2 is also traced in Ti-22Al-21Nb-6Zr. The improved oxidation resistance for Ti-22Al-26Nb-1Zr can be ascribed to the refinement of oxides. While in Ti-22Al-21Nb-6Zr alloy, although formation of Al2O3 is obvious at 800 oC, ZrO2 in the scale can provide sites for rapid oxygen transport, leading to the high mass gain |
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Keywords: | oxidation kinetics zirconium Ti2AlNb-based alloy oxide scale |
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