| N,N—二丁基邻乙基苯胺合成的研究 |
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| 引用本文： | 孟艳秋,赵鸣玉.N,N—二丁基邻乙基苯胺合成的研究[J].沈阳化工学院学报,1999,13(2):143-146. |
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| 作者姓名： | 孟艳秋 赵鸣玉 |
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| 作者单位： | 沈阳化工学院精细化工系 |
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| 基金项目： | 沈阳市科委重点科研项目基金,沈阳市环保局重点科研项目基金 |
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| 摘 要： | 以氯霉素生产过程中乙苯硝经的副产物邻硝基乙苯为原料，经铁酸法还原，相转移催化Ｎ－烷基化反应合成了Ｎ，Ｎ－二丁基邻乙基苯胺。考察反应时间，反应物配比，催化剂用量对芳胺Ｎ－烷基化反应产物产率的影响。
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| 关 键 词： | 邻硝基乙苯 合成 烷基化 苯胺 |
Study on the Synthesis of N,N\|dibutyl\|\%o\%\|ethylaniline |
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| MENG Yan\|qiu,\ ZHAO Ming\|yu,\ ZHANG Da\|yang.Study on the Synthesis of N,N\|dibutyl\|\%o\%\|ethylaniline[J].Journal of Shenyang Institute of Chemical Technolgy,1999,13(2):143-146. |
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| Authors: | MENG Yan\|qiu \ ZHAO Ming\|yu \ ZHANG Da\|yang |
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| Abstract: | N,N\|dibutyl\|\%o\%\|ethylaniline was synthesized by reduction and alkylation using by\|product of chloramphenicol as raw materials. The optimum reaction conditions of synthesis are as follows: (1)the molar ratio of \%o\%\|ethylaniline to \%n\%\|butyl bromide :12.4;\ (2)reaction time: 16 hours;\ (3)weigh of catalyst:1.2 gram. Under the condition, the yield of N,N\|dibutylaniline is 45.8%. The structure was determined by IR and \ 1 H\|NMR.\= |
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| Keywords: | o\%\|nitro\|ethylbenzene \ synthesis \ alkylation |
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