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Synthesis and luminescence properties of SrAleO4:Eue+,Dy3+ hollow microspheres via a solvothermal co-precipitation method
引用本文:薛志萍,邓苏青,刘应亮,雷炳富,肖勇,郑明涛. Synthesis and luminescence properties of SrAleO4:Eue+,Dy3+ hollow microspheres via a solvothermal co-precipitation method[J]. 中国稀土学报(英文版), 2013, 31(3): 241-246. DOI: 10.1016/S1002-0721(12)60265-8
作者姓名:薛志萍  邓苏青  刘应亮  雷炳富  肖勇  郑明涛
作者单位:Department of Chemistry,Jinan University;College of Science,South China Agricultural University
基金项目:Project supported by National Natural Science Foundation of China (21071063,21171071)
摘    要:
SrAl2O4:Eu2+,Dy3+ hollow microspheres were successfully prepared through a facile and mild solvothermal co-precipitation combining with a postcalcining process.The structure and particle morphology were investigated by X-ray diffraction(XRD),scanning and transmission electron microscopy(SEM and TEM)pictures,respectively.The mechanism for the formation of spherical SrAl2O4:Eu2+,Dy3+ phosphor was preliminary presented.After being irradiated with ultraviolet(UV)light,the spherical phosphor emitted long-lasting green phosphorescence.Both the photoluminescence(PL)spectra and luminance decay,compared with that of commercial bulky powders,revealed that the phosphors had efficient luminescent and long lasting properties.It was considered that the SrAl2O4:Eu2+,Dy3+ hollow microspheres had promising long-lasting phosphorescence with potential scale-dependent applications in photonic devices.

关 键 词:SrAl2O4:Eu2+,Dy3+  hollow microsphere  luminescence  long-lasting phosphor  rare earths
收稿时间:2012-12-12

Synthesis and luminescence properties of SrAl2O4:Eu2+,Dy3+ hollow microspheres via a solvothermal co-precipitation method
XUE Zhiping , DENG Suqing , LIU Yingliang , LEI Bingfu , XIAO Yong , ZHENG Mingtao. Synthesis and luminescence properties of SrAl2O4:Eu2+,Dy3+ hollow microspheres via a solvothermal co-precipitation method[J]. Journal of Rare Earths, 2013, 31(3): 241-246. DOI: 10.1016/S1002-0721(12)60265-8
Authors:XUE Zhiping    DENG Suqing    LIU Yingliang    LEI Bingfu    XIAO Yong    ZHENG Mingtao
Affiliation:1.Department of Chemistry,Jinan University,Guangzhou 510632,China;2.College of Science,South China Agricultural University,Guangzhou 510642,China)
Abstract:
SrAl2O4:Eu2+,Dy3+ hollow microspheres were successfully prepared through a facile and mild solvothermal co-precipitation combining with a postcalcining process. The structure and particle morphology were investigated by X-ray diffraction (XRD), scanning and transmission electron microscopy (SEM and TEM) pictures, respectively. The mechanism for the formation of spherical SrAl2O4:Eu2+,Dy3+ phosphor was preliminary presented. After being irradiated with ultraviolet (UV) light, the spherical phosphor emitted long-lasting green phosphorescence. Both the photoluminescence (PL) spectra and luminance decay, compared with that of commercial bulky powders, revealed that the phosphors had efficient luminescent and long lasting properties. It was considered that the SrAl2O4:Eu2+,Dy3+ hollow microspheres had promising long-lasting phosphorescence with potential scale-dependent applications in photonic devices.
Keywords:2+ 3+SrA1204:Eu ,Dy  hollow mmrosphere  luminescence  long-lasting phosphor  rare earths
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