| 利用废旧锌锰电池制取锌盐和氧化锌的研究 |
| |
| 引用本文： | 白晓波,赵东江,马松艳.利用废旧锌锰电池制取锌盐和氧化锌的研究[J].应用化工,2007,36(8):839-841. |
| |
| 作者姓名： | 白晓波 赵东江 马松艳 |
| |
| 作者单位： | 绥化学院,化学系,黑龙江,绥化,152061 |
| |
| 基金项目： | 绥化学院校科研和教改项目 |
| |
| 摘 要： | 以废旧锌锰电池为研究对象,采用湿法回收技术,制备ZnSO4.7H2O,ZnCO3和ZnO。结果表明,Zn溶解时间随着H2SO4浓度而变,当H2SO4浓度为3 mol/L时,溶解耗时仅为5 h,ZnSO4.7H2O产率可达93.44%。在Na2CO3,NaHCO3,(NH4)2CO3三种沉淀剂中,(NH4)2CO3的沉淀效果最好,制备的ZnCO3颗粒细小,在1 073.2 K条件下,其分解效率可达88.75%。
|
| 关 键 词： | 氧化锌 废旧Zn-Mn电池 Zn回收 浸泡 |
| 文章编号： | 1671-3206（2007）08-0839-03 |
| 修稿时间： | 2007-06-04 |
Study on producing zinc salts and zinc oxide using the wasted Zn-Mn battery |
| |
| BAI Xiao-bo,ZHAO Dong-jiang,MA Song-yan.Study on producing zinc salts and zinc oxide using the wasted Zn-Mn battery[J].Applied chemical industry,2007,36(8):839-841. |
| |
| Authors: | BAI Xiao-bo ZHAO Dong-jiang MA Song-yan |
| |
| Affiliation: | Department of Chemistry, Suihua College, Suihua 152061, China |
| |
| Abstract: | The wasted Zn-Mn batteries are disposed by the hydrometallurgy recycling technology.It gets ZnSO4·7H2O,ZnCO3 and ZnO from the wasted Zn-Mn battry.The experimental results showed that the Zn dissolving time is influenced by concentration of H2SO4.When concentration of H2SO4 is 3 mol/L,the dissolving time is only 5 h and the yield of ZnSO4·7H2O can reach 93.44%.The precipitating effect of(NH4)2CO3 is best among Na2CO3,NaHCO3,(NH4)2CO3 precipitators,the decomposing efficiency can reach 88.75% at 1 073.2K. |
| |
| Keywords: | zinc oxide wasted Zn-Mn battery Zn recovery marinating |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
|
