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锂盐在铝电解中的作用
引用本文:曹大力,邱竹贤,王吉坤,石忠宁,阚红敏,班允刚,王兆文.锂盐在铝电解中的作用[J].材料导报,2006,20(8):90-93.
作者姓名:曹大力  邱竹贤  王吉坤  石忠宁  阚红敏  班允刚  王兆文
作者单位:1. 东北大学材料与冶金学院,沈阳,110006;沈阳化工学院材料科学与工程学院,沈阳,110141;云南冶金集团总公司科技部,昆明,650016
2. 东北大学材料与冶金学院,沈阳,110006
3. 沈阳化工学院材料科学与工程学院,沈阳,110141
基金项目:国家重点基础研究发展计划(973计划),国家自然科学基金,辽宁省博士科研项目
摘    要:报道了锂盐在铝电解中的作用.阐述了其提高熔体的电导率,降低电解质的熔点,减少铝的溶解损失,减小极化电压,降低电解质的蒸气压及延长阴极寿命等优点.提出锂盐与其它添加剂的有机结合,可获得更大经济效益和社会效益的构想.

关 键 词:铝电解  锂盐(LiF/Li2CO3)  添加剂

Effects of Additive Lithium Salts on Aluminum Electrolysis
CAO Dali,QIU Zhuxian,WANG Jikun,SHI Zhongning,KAN Hongmin,BAN Yungang,WANG Zhaowen.Effects of Additive Lithium Salts on Aluminum Electrolysis[J].Materials Review,2006,20(8):90-93.
Authors:CAO Dali  QIU Zhuxian  WANG Jikun  SHI Zhongning  KAN Hongmin  BAN Yungang  WANG Zhaowen
Affiliation:1. Materials and Merallurgy School, Northeastern University, Shenyang 110006 ; 2. Materials Science and Engineering College,Shenyang Institute of Chemical Technology,Shenyang 110141; 3. Science and Technology Departnent,Yunnan Metallurgy Group,Kunming 650016
Abstract:The effects of additive lithium salts on aluminum electrolysis are reported. The main advantages of additive lithium salts to aluminum electrolysis are that increasing electrical conductivity of melts, decreasing the melting point of electrolyte, decreasing aluminum dissolved in cryolite melts, decreasing polarixation voltage, depressing vapour pressures of electrolyte and prolonging life of cathode. One assumption is put forward that emormous economic and environmental benefits will he acquired when lithium salts and other additives are appropriately added to the electrolysis cell.
Keywords:aluminum electrolysis  lithium salts(LiF/Li_2CO_3)  additive
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