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| 混合配体Cd-MOF的合成及其光催化降解性能 | |
| 引用本文： | 陈颖,翟勃银,梁宇宁,张宏宇. 混合配体Cd-MOF的合成及其光催化降解性能[J]. 硅酸盐学报, 2019, 47(4): 433-439 |
| 作者姓名： | 陈颖 翟勃银 梁宇宁 张宏宇 |
| 作者单位： | 东北石油大学化学化工学院,石油与天然气化工省重点实验室,黑龙江大庆 163318;大庆石化公司炼油厂,黑龙江大庆,163711 |
| 摘 要： | 以四水硝酸镉、均苯三甲酸、乳酸和N,N-二甲基甲酰胺为原料,采用溶剂热合成方法,制备得到混合配体Cd-金属有机框架(MOF)材料。利用偏光显微镜、扫描电子显微镜、热重分析仪、Fourier红外光谱、X射线衍射仪、N_2吸附–脱附分析、紫外–可见漫反射光谱等手段对其进行表征。以亚甲基蓝(MB)溶液为模拟污染物,室温条件下考察了该材料在紫外光下的光催化活性。研究表明:当混合配体Cd-MOF作为光催化剂时,当其用量为70 mg,MB初始浓度为40 mg/L、pH=8～10时,在2 h内降解率可达80%左右,而且混合配体Cd-MOF经过5次循环试验后仍能保持较稳定的光催化活性。 |
| 关 键 词： | 混合配体Cd-MOF 合成 表征 光催化降解性能 |
Preparation of Mixed Ligand Cd-MOF and Its Photocatalytic Performance |
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| CHEN Ying,ZHAI Boyin,LIANG Yuning,ZHANG Hongyu. Preparation of Mixed Ligand Cd-MOF and Its Photocatalytic Performance[J]. Journal of The Chinese Ceramic Society, 2019, 47(4): 433-439 | |
| Authors: | CHEN Ying ZHAI Boyin LIANG Yuning ZHANG Hongyu |
| Affiliation: | (School of Chemistry and Chemical Engineering,Northeast Petroleum University,Key Laboratory of Petroleum and NaturalGas Chemical Industry,Daqing 163318,Heilongjiang,China;Daqing Petrochemical Company Refinery,Daqing 163711,Heilongjiang,China) |
| Abstract: | CHEN Ying;ZHAI Boyin;LIANG Yuning;ZHANG Hongyu(School of Chemistry and Chemical Engineering,Northeast Petroleum University,Key Laboratory of Petroleum and NaturalGas Chemical Industry,Daqing 163318,Heilongjiang,China;Daqing Petrochemical Company Refinery,Daqing 163711,Heilongjiang,China) |
| Keywords: | mixed ligand Cd-MOF synthesis characterization photocatalytic degradation performance |
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